Which version of FreeRTOS-LTS should I use with v2022.2 Vitis Xilinx FreeRTOS port ( v10.4.6 kernel )?

Since you are on a Zynq UltraScale+MPSoC which runs Cortex A53 64Gb , you should be using Xilinx Ultrascale Network interface.
It mentions here in the readme .

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